A mapping of the electron localization function for the silica polymorphs: evidence for domains of electron pairs and sites of potential electrophilic attack     

G. V. Gibbs  D. F. Cox  T. D. Crawford  M. B. Boisen Jr  M. Lim 《Physics and Chemistry of Minerals》2002,29(5):307-318

The electron localization function, η, evaluated for first-principles geometry optimized model structures generated for quartz and coesite, reveals that the oxide anions are coordinated by two hemispherically shaped η-isosurfaces located along each of the SiO bond vectors comprising the SiOSi angles. With one exception, they are also coordinated by larger banana-shaped isosurfaces oriented perpendicular to the plane centered in the vicinity of the apex of each angle. The hemispherical isosurfaces, ascribed to domains of localized bond-pair electrons, are centered ～0.70 Å along the bond vectors from the oxide anions and the banana-shaped isosurfaces, ascribed to domains of localized nonbonding lone-pair electrons, are centered ～0.60 Å from the apex of the angle. The oxide anion comprising the straight SiOSi angle in coesite is the one exception in that the banana-shaped isosurface is missing; however, it is coordinated by two hemispherically shaped isosurfaces that lie along the bond vectors. In the case of a first-principles model structure generated for stishovite, the oxide anion is coordinated by five hemispherically shaped η-isosurfaces, one located along each of the three SiO bond vectors (ascribed to domains of bonding-electron pairs) that are linked to the anion with the remaining two (ascribed to domains of nonbonding-electron pairs) located on opposite sides of the plane defined by three vectors, each isosurface at a distance of ～0.5 Å from the anion. The distribution of the five isosurfaces is in a one-to-one correspondence with the distribution of the maxima displayed by experimental Δρ and theoretical ??²ρ maps. Isosurface η maps calculated for quartz and the (HO) ₃ SiOSi(OH) ₃ molecule also exhibit maxima that correspond with the (3,?3) maxima displayed by distributions of ??²ρ. Deformation maps observed for the SiOSi bridges for the silica polymorphs and a number of silicates are similar to that calculated for the molecule but, for the majority, the maxima ascribed to lone-pair features are absent. The domains of localized nonbonding-electron pair coordinating the oxide anions of quartz and coesite provide a basis for explaining the flexibility and the wide range of the SiOSi angles exhibited by the silica polymorphs with four-coordinate Si. They also provide a basis for explaining why the SiO bond length in coesite decreases with increasing angle. As found in studies of the interactions of solute molecules with a solvent, a mapping of η-isosurfaces for geometry-optimized silicates is expected to become a powerful tool for deducing potential sites of electrophilic attack and reactivity for Earth materials. The positions of the features ascribed to the lone pairs in coesite correspond with the positions of the H atoms recently reported for an H-doped coesite crystal.  相似文献   

Vertebrate burrows in late Pleistocene paleosols at Korean Palaeolithic sites and their significance as a stratigraphic marker     

Hyoun Soo Lim  Yong Il Lee  Cheong-Bin Kim  Heon-Jong Lee 《Quaternary Research》2007,68(2):213-219

A vertebrate burrow-bearing layer of late Pleistocene age is commonly found at many Paleolithic archaeological sites in Korea. The burrows are straight to slightly curved in horizontal (plan) view and gently inclined in lateral (sectional) view. They are interpreted as having been produced by rodent-like mammals based on their size and architecture. The significance of such burrow-bearing layers as a characteristic stratigraphic marker unit is demonstrated by high burrow abundance, consistent stratigraphic position, lack of stratigraphic recurrence at these sites, and widespread geographic extent. Three dating methods, tephrochronology, radiocarbon, and OSL dating, were used to infer the age of these burrow-bearing layers. The dating results indicate that they were formed between ca. 40,000 and 25,000 yr (MIS 3−2), and this suggests that this layer can be used as a stratigraphic time-marker in late Pleistocene paleosol sequences for this region.  相似文献   

Characteristics of tephra in Holocene lake sediments on King George Island, West Antarctica: implications for deglaciation and paleoenvironment     

Yong Il Lee  Hyoun Soo Lim  Ho Il Yoon  Andrzej Tatur 《Quaternary Science Reviews》2007,26(25-28):3167-3178

Several reworked tephra layers in gravity-flow deposits are present in lacustrine core sediments collected from Hotel and Rudy Lakes on King George Island, South Shetland Islands, maritime sub-Antarctica. This study tests the values of tephra for establishing regional tephrochronologies for lakes in ice-covered landscapes in the vicinity of volcanoes. The tephra record is more abundant in a long Hotel Lake core (515 cm long). This study uses volcanic glass samples from five tephra layers of Hotel Lake and from one tephra layer of Rudy Lake. Morphologically, tephras are mixtures of basaltic and pumice shards, both having various degrees of vesicularity. Major element analyses of glass shards reveal that the majority of the glass fragments belong to basic glass (<60 wt% SiO₂), compositionally ranging from basalt to low-silica andesite and subalkaline series medium-K tholeiites, probably sourced from Deception Island located 130 km southwest of King George Island. Less than 20% of tephra belongs to silicic glass and occurs in three tephra horizons E of Hotel Lake. However, source volcano(es) for about 10% of basic tephra and silicic tephra are not readily identified from nearby volcanic centers. Except for the studied tephra in Rudy Lake, all tephra samples in Hotel Lake are not ashfall deposits but reworked and redeposited pyroclasts derived from retreating ice sheet, resulting in the occurrence of geochemically equivalent tephra samples in different tephra horizons. The dating of the studied tephra horizons represents the timing of deglaciation rather than that of volcanic eruptions. The result of this study implies that combined with sedimentological information more chemical criterion is necessary to study tephrochronology and regional correlation and to understand paleoenvironmental changes using tephra.  相似文献   

Genetic relationship of metamorphic reaction and dehydration-melting     

Fulai Liu  Qihan Shen  Yuansheng Eng  Xuechun Xu  Rui Ma 《中国科学D辑(英文版)》1998,41(1):49-56

The high-temperature and pressure experimental data of garnet, sillimantite and biotite-bearing potash feldspar gneiss (SGBG, natural block rock) has shown that metamorphic reactions between garnet and melt, and mineral assemblage evolutional features are not only controlled byP-T condition, but also genetically correlate with dehydration-melting of biotite and partial melting of felsic minerals. Combining experimental data with theoretical analyses, the genetic mechanism of metamorphic reaction and its dynamic significance have been demonstrated in the process of metamorphic evolution of khondalite series on the border of Jin (Shanxi Province)-Inner Mongolia. Project supported by the Youth Geologist Foundation of Ministry of Geology and Mineral Resources of China, the Post-docter Foundation and the National Natural Science Foundation of China (Grant No. 49572138).  相似文献   

Rare earth elements in bottom sediments of major rivers around the Yellow Sea: implications for sediment provenance     

Zhaokai Xu  Dhongil Lim  Jinyong Choi  Shouye Yang  Hoisoo Jung 《Geo-Marine Letters》2009,29(5):291-300

Rare earth elements (REEs) of 91 fine-grained bottom sediment samples from five major rivers in Korea (the Han, Keum, and Yeongsan) and China (the Changjiang and Huanghe) were studied to investigate their potential as source indicator for Yellow Sea shelf sediments, this being the first synthetic report on REE trends for bottom sediments of these rivers. The results show distinct differences in REE contents and their upper continental crust (UCC)-normalized patterns: compared to heavy rare earth elements (HREEs), light rare earth elements (LREEs) are highly enriched in Korean river sediments, in contrast to Chinese river sediments that have a characteristic positive Eu anomaly. This phenomenon is observed also in primary source rocks within the river catchments. This suggests that source rock composition is the primary control on the REE signatures of these river sediments, due largely to variations in the levels of chlorite and monazite, which are more abundant in Korean bottom river sediments. Systematic variations in ΣLREE/ΣHREE ratios, and in (La/Yb)–(Gd/Yb)_UCC but also (La/Lu)–(La/Y)_UCC and (La/Y)–(Gd/Lu)_UCC relations have the greatest discriminatory power. These findings are consistent with, but considerably expand on the limited datasets available to date for suspended sediments. Evidently, the REE fingerprints of these river sediments can serve as a useful diagnostic tool for tracing the provenance of sediments in the Yellow Sea, and for reconstructing their dispersal patterns and the circulation system of the modern shelf, as well as the paleoenvironmental record of this and adjoining marginal seas.  相似文献   

Scientific field training for human planetary exploration     

D.S.S. Lim  G.L. Warman  C.P. McKay  M.M. Marinova  D. Andersen  Z. Cardman  M.D. Delaney  A.L. Forrest  B.E. Laval  P. Nuytten  M. Reay  D. Schulze-Makuch  G.F. Slater 《Planetary and Space Science》2010,58(6):920-930

Forthcoming human planetary exploration will require increased scientific return (both in real time and post-mission), longer surface stays, greater geographical coverage, longer and more frequent EVAs, and more operational complexities than during the Apollo missions. As such, there is a need to shift the nature of astronauts’ scientific capabilities to something akin to an experienced terrestrial field scientist. To achieve this aim, the authors present a case that astronaut training should include an Apollo-style curriculum based on traditional field school experiences, as well as full immersion in field science programs. Herein we propose four Learning Design Principles (LDPs) focused on optimizing astronaut learning in field science settings. The LDPs are as follows:

(1)

LDP#1: Provide multiple experiences: varied field science activities will hone astronauts’ abilities to adapt to novel scientific opportunities

(2)

LDP#2: Focus on the learner: fostering intrinsic motivation will orient astronauts towards continuous informal learning and a quest for mastery

(3)

LDP#3: Provide a relevant experience—the field site: field sites that share features with future planetary missions will increase the likelihood that astronauts will successfully transfer learning

(4)

LDP#4: Provide a social learning experience—the field science team and their activities: ensuring the field team includes members of varying levels of experience engaged in opportunities for discourse and joint problem solving will facilitate astronauts’ abilities to think and perform like a field scientist.

The proposed training program focuses on the intellectual and technical aspects of field science, as well as the cognitive manner in which field scientists experience, observe and synthesize their environment. The goal of the latter is to help astronauts develop the thought patterns and mechanics of an effective field scientist, thereby providing a broader base of experience and expertise than could be achieved from field school alone. This will enhance their ability to execute, explore and adapt as in-field situations require.  相似文献   

Use of fluorescein as a ground water tracer in brackish water aquifers     

Chua LH  Robertson AP  Yee WK  Shuy EB  Lo EY  Lim TT  Tan SK 《Ground water》2007,45(1):85-88

A drift and pumpback experiment was conducted in a brackish water sandfill. The sandfill was reclaimed from the sea in the eastern part of Singapore and contains sands with low organic and clay/silt contents. The high salinity in the ground water precludes the use of chloride and bromide as tracers in such an environment, and a field experiment was conducted to assess the viability of using fluorescein as a tracer in brackish water aquifers. Nitrate was used as a second tracer to serve as a check. Initial laboratory studies showed that fluorescence was unaffected over the range of electrical conductivity and pH of the ground water. Results from the field experiment show that fluorescein appears to behave conservatively.  相似文献   

Analysis and characterization of the synergistic AIRS and MODIS cloud-cleared radiances     

Hong Zhang  Hung-Lung Huang  Agnes Lim  Robert Holz  Steve Dutcher  Fred Nagle  Liam Gumley  Jinnian Wang  Runhe Shi  Wei Gao 《Frontiers of Earth Science》2010,4(3):363-373

The Atmospheric Infrared Sounder (AIRS) and MODerate-Resolution Imaging Spectroradiometer (MODIS) on board NASA Earth Observing System (EOS) Aqua spacecraft measure the upwelling infrared radiance used for numerous remote-sensing- and climate-related applications. AIRS provides high spectral resolution infrared radiances, while MODIS provides collocated high spatial resolution radiances at 16 broad infrared bands. An optimal algorithm for cloud-clearing has been developed for AIRS cloudy soundings at the University of Wisconsin-Madison, where the spatially and spectrally collocated AIRS and MODIS data has been used to analyze the characteristic of this algorithm. An analysis and characterization of the global AIRS cloud-cleared radiances using the bias and the standard deviation between the cloud-cleared and the nearby clear measurements are studied. Scene inhomogeneity for both land- and water-surface types has been estimated to account for the assessed error. Both monthly and seasonal changes of global AIRS/MODIS cloud-clearing performance also have been analyzed.  相似文献   

Effects of natural and calcined oyster shells on Cd and Pb immobilization in contaminated soils   总被引：5，自引：0，他引：5  

Yong Sik Ok  Sang-Eun Oh  Mahtab Ahmad  Seunghun Hyun  Kwon-Rae Kim  Deok Hyun Moon  Sang Soo Lee  Kyoung Jae Lim  Weon-Tai Jeon  Jae E. Yang 《Environmental Earth Sciences》2010,61(6):1301-1308

In Korea, soils adjacent to abandoned mines are commonly contaminated by heavy metals present in mine tailings. Further, the disposal of oyster shell waste by oyster farm industries has been associated with serious environmental problems. In this study, we attempted to remediate cadmium (Cd)- and lead (Pb)-contaminated soils typical of those commonly found adjacent to abandoned mines using oyster shell waste as a soil stabilizer. Natural oyster shell powder (NOSP) and calcined oyster shell powder (COSP) were applied as soil amendments to immobilize Cd and Pb. The primary components of NOSP and COSP are calcium carbonate (CaCO₃) and calcium oxide (CaO), respectively. X-ray diffraction, X-ray fluorescence and scanning electron microscope analyses conducted in this study revealed that the calcination of NOSP at 770°C converted the less reactive CaCO₃ to the more reactive CaO. The calcination process also decreased the sodium content in COSP, indicating that it was advantageous to use COSP as a liming material in agricultural soil. After 30 days of incubation, we found that the 0.1 N HCl-extractable Cd and Pb contents in soil decreased significantly as a result of an increase in the soil pH and the formation of metal hydroxides. COSP was more effective in immobilizing Cd and Pb in the contaminated soil than NOSP. Overall, the results of this study suggest that oyster shell waste can be recycled into an effective soil ameliorant.  相似文献   

The effect of the wintertime Arctic Oscillation on springtime vegetation over the northern high latitude region   总被引：1，自引：0，他引：1  

Mee-Hyun Cho  Gyu-Ho Lim  Hyo-Jong Song 《Asia-Pacific Journal of Atmospheric Sciences》2014,50(1):567-573

The winter Arctic Oscillation (AO), a major source of climate variability in the Northern Hemisphere, affects winter and the subsequent spring climate over northern high latitude. Such effects are evident even in the 1st eigenmode of the normalized difference vegetation index (NDVI). The impacts of the winter AO is a dipole pattern between Eurasia and North America; positive (negative) values of the winter AO induce warmer (cooler) and high (low) vegetation activity in the following spring over Eurasia (North America). Regarding the time-lagged response of vegetation, the sea surface temperature (SST) and snow cover contribute to maintaining the large-scale circulation anomaly associated with the AO.  相似文献